Sucre, Bolivia. Known as the "White City," Sucre is the constitutional capital of Bolivia and a destination rich in history, culture, and colonial charm. Declared a UNESCO World Heritage Site, this picturesque city boasts stunning colonial architecture, cobblestone streets, and a vibrant culinary and artistic scene. With its pleasant climate and peaceful atmosphere, Sucre is the perfect place to explore museums, churches, and traditional markets while immersing yourself in its rich cultural heritage.